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Waterloo Chronicle, 8 Aug 2019, p. 004

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"On ly t he Bes t fr om our Fam ily to Y our s" w w w . s t e m m l e r m e a t s . c a 3031 labsinger line, heidelberg mon.-Wed. 8-6; thurs.-fri. 8-8; Sat. 7:30-5 519-699-4590 Serge Petrusic BSc, DCh, Chiropodist Visit kwfoot.com to learn more or call 519-884-4200 279 Weber St. N. Suite 17 Waterloo, ON N2J 3H8 519-884-4200 kwfoot.com Doctors referral not necessary Are you tired of heel pain? • Custom Orthotics / Knee Braces • Flat Feet / High Arched Feet • Heel Pain / Plantar Fasciitis / Bunions • Laser Therapy for Pain and ammation • Laser Therapy for Fungal Nails, Warts and Corns • Nail Problems (fungal, ingrown) Services covered under extended health plans Also services for ... • Warts, Corns, Calluses • Diabetic Foot Care • Senior's Foot Care & ... more We offer a unique treatment protocol for heel pain which is exclusive to our clinic and has an excellent success rate. Each program is tailored according to the patient and it is specifically designed to treat and prevent the return of the problem.We have incorporated the latest laser technology in our treatment plans in order to achieve the best possible results. WATERLOO -- What is soft is strong. It may sound like a paradox but the ancient Chinese philoso- pher Laozi purportedly used this phrase to describe water, which is soft and yielding but can eventu- ally erode even the largest of rocks. Now a team of researchers at the University of Waterloo is poised to take that paradox and make it a reality. A new polymer developed by UW chemical engineering PhD students is able to switch states between a soft gel and a hard solid within minutes while at the same room temperature, and it could revolutionize the robotics and ad- hesive industries. The researchers combined a supercooled salt solution with a super absorbent polymer gel commonly found inside baby dia- pers to create a material that is soft and flexible, but can be made super strong and rigid on de- mand. The polymer, referred to as sal- gel, can achieve the transforma- tion within a wide temperature range, from -90 C to 58?C, and is reversible by simply applying di- rect heat. "With traditional materials you only have one property for a given temperature, but now we have two properties," said Kuo Yang, the chemical engineering PhD student who developed the idea. "There is still a lot of work to be done, but this is a very promis- ing first step." A phenomenon known as su- percooling is at the core of the transformation. It involves reduc- ing the temperature of the salt so- lution below the normal freezing point of water before combining it with the polymer. The material wants to freeze and crystalize, but the salt inside the polymer isn't able to arrange itself into a crys- talized form. Simply touching another salt crystal to the gel provides the nec- essary road map, however, and ac- tivates the reaction. The gel solid- ifies in just minutes. "All the molecules in the liquid want to arrange into a crystal, but they can't find a way to align themselves," said Yang. "Once you show them a crystal, they re- alize 'oh that's how we arrange ourselves'." The process is called nucle- ation and it transforms the gel in- to a rigid, opaque material; it es- sentially freezes while still at room temperature, Yang said. The two-in-one polymer could revolutionize robotics by giving machines the soft and flexible touch needed to grip delicate or fragile items, and then the strength and rigidity necessary to pick them up. Researchers also envision us- ing it as an adhesive by attaching the gel to the contours of a sur- face, hardening it to create a strong bond, then releasing the bond when necessary. Their tests found the solid state is approxi- mately 10,000 times stronger than the gel form. They're on the cusp of resolv- ing the paradox that something soft and flexible cannot also be strong, said their professor, Boxin Zhao, a chemical engineer who helped direct their work. "This material can do both," he said. "That's fundamentally very important." Aleksander Cholewinski, a PhD student in chemical engi- neering and member of the re- search team, said early tests show the process also doesn't appear to weaken the polymer bonds after repeated cycles. "We've done multiple freeze- melt, freeze-melt cycles and we've actually seen it get slightly stron- ger in the frozen state," he said. "And when you go back to the melted (form) it isn't damaged." It took about four months to perfect the process, and about a year overall to publish the results. The pair collaborated with post-doctoral fellows Li Yu and Geoffrey Rivers on the research. Their paper, "A hybrid material that reversibly switches between two stable solid states" was re- cently published in the journal Nature Materials. NEW POLYMER DEVELOPED AT THE UNIVERSITY OF WATERLOO CAN EXIST AS BOTH A SOLID AND A GEL JAMES JACKSON jjackson@therecord.com LOCAL Aleksander Cholewinski holds sal-gel in a rigid and gel state at the University of Waterloo on Tuesday. The chemical engineering PhD student was part of a team that developed a polymer that can switch back and forth between the two states. Mathew McCarthy/Torstar

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